Allylation is the enantioselective, iridium-catalyzed addition of an allyl group to an alcohol or aldehyde, producing a secondary homoallylic alcohol as a consequence. When employing aldehyde reactants, primary alcohol dehydrogenation or hydrogen transfer from 2-propanol is the mechanism of the Krische allylation. The Krische allylation allows for the direct conversion of primary alcohols to secondary homoallylic alcohols without the need of preformed allyl metal reagents, in contrast to other allylation techniques (precluding alcohol to aldehyde oxidation). The production of polyketide natural compounds typically uses enantioselective carbonyl allylations. Hoffmann reported the first asymmetric carbonyl allylation in 1978 using an allylborane produced from camphor and a chiral allylmetal reagent. Later, Kumada, Roush, Brown, Leighton, and others produced more chiral allylmetal reagents.
Stanislaw Dzwigaj
Sorbonne University, France
Anne M Gaffney
University of South Carolina, United States
Marta I Litter
Sapienza University of Rome, Italy
Dai Yeun Jeong
Jeju National University, Korea, Republic of
Sergey Suchkov
N.D. Zelinskii Institute for Organic Chemistry of the Russian Academy of Sciences, Russian Federation
Vladislav Sadykov
Novosibirsk State University, Russian Federation
Enrico Paris
CREA-IT & DIAEE, Italy
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Dai Yeun Jeong, Jeju National University, Korea, Republic of
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Vladislav Sadykov, Novosibirsk State University, Russian Federation
Title : Effective B2O3 modified Ni/Al2O3 co precipitated catalysts for waste cooking oil transformation into green diesel
Eleana Kordouli, University of Patras, Greece
Title : Personalized and Precision Medicine (PPM) as a unique healthcare model through Bi-odesign-Inspired Bio- and chemical engineering applications to secure the human healthcare and biosafety: Engineering of biocatalysts - from evolution to creation
Sergey Suchkov, N.D. Zelinskii Institute for Organic Chemistry of the Russian Academy of Sciences, Russian Federation
Title : Sonophotocatalysis in advanced oxidation process: A short review
Collin G Joseph, University Malaysia Sabah, Malaysia
Title : Development of CSM recovery methods based on their adsorption on biochar from lignocellulosic residues
Bintou Sanagare, Universite de Quebec a Trois-Rivieres , Canada