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Allylation

Allylation is the enantioselective, iridium-catalyzed addition of an allyl group to an alcohol or aldehyde, producing a secondary homoallylic alcohol as a consequence. When employing aldehyde reactants, primary alcohol dehydrogenation or hydrogen transfer from 2-propanol is the mechanism of the Krische allylation. The Krische allylation allows for the direct conversion of primary alcohols to secondary homoallylic alcohols without the need of preformed allyl metal reagents, in contrast to other allylation techniques (precluding alcohol to aldehyde oxidation). The production of polyketide natural compounds typically uses enantioselective carbonyl allylations. Hoffmann reported the first asymmetric carbonyl allylation in 1978 using an allylborane produced from camphor and a chiral allylmetal reagent. Later, Kumada, Roush, Brown, Leighton, and others produced more chiral allylmetal reagents.

Committee Members
Speaker at International Conference on Catalysis, Chemical Engineering and Technology 2025 - Ephraim Suhir

Ephraim Suhir

Portland State University, United States
Speaker at International Conference on Catalysis, Chemical Engineering and Technology 2025 - Thomas J J Muller

Thomas J J Muller

Heinrich-Heine-Universitat Dusseldorf, Germany
Speaker at International Conference on Catalysis, Chemical Engineering and Technology 2025 - Stanislaw Dzwigaj

Stanislaw Dzwigaj

Sorbonne University, France
Speaker at International Conference on Catalysis, Chemical Engineering and Technology 2025 - Dai Yeun Jeong

Dai Yeun Jeong

Jeju National University, Korea, Republic of
CCT 2025 Speakers
Speaker at International Conference on Catalysis, Chemical Engineering and Technology 2025 - Haibo Ge

Haibo Ge

Texas Tech University, United States
Speaker at International Conference on Catalysis, Chemical Engineering and Technology 2025 - Marta I Litter

Marta I Litter

University of General San Martin, Argentina
Speaker at International Conference on Catalysis, Chemical Engineering and Technology 2025 - Luigi Antonio Pezone

Luigi Antonio Pezone

Santa Maria Capua Vetere, Italy
Speaker at International Conference on Catalysis, Chemical Engineering and Technology 2025 - Davide Frumento

Davide Frumento

RomaTre University, Italy

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