Over the past 10 years, there has been rapid advancement in the production of C-C bonds by carbometallation, particularly in reactions that are promoted by group 8–11 metals. It is now possible to securely design inter- and intramolecular processes, as well as sequences that combine the two, to produce useful substrates like carbo- and heterocycles. It was discovered that when imidazole was deprotonated with potassium t-butoxide in liquid ammonia via electrochemically induced SRN1, direct C-C bond formation at the 2-position of imidazole and benzimidazole occurred. Over the past 10 years, there has been rapid advancement in the production of C-C bonds by carbometallation, particularly in reactions that are promoted by group 8–11 metals. It is now possible to securely design inter- and intramolecular processes, as well as sequences that combine the two, to produce useful substrates like carbo- and heterocycles.
Title : Personalized and Precision Medicine (PPM) as a unique healthcare model via design-driven bio- and chemical engineering view of biotech
Sergey Suchkov, R&D Director of the National Center for Human Photosynthesis, Mexico
Title : Catalytic one-pot multicomponent syntheses of functional chromophores – Synthetic efficiency meets functionality design
Thomas J J Muller, Heinrich-Heine-Universitat Dusseldorf, Germany
Title : Use of iron nanomaterials for the treatment of metals, metalloids and emergent contaminants in water
Marta I Litter, University of General San Martin, Argentina
Title : The roles and capacity building of NGOs as agents responding to climate change
Dai Yeun Jeong, Jeju National University, Korea, Republic of
Title : Application of metal single-site zeolite catalysts in heterogeneous catalysis
Stanislaw Dzwigaj, Sorbonne University, France
Title : From photocatalysis to photon-phonon co-driven catalysis for inert molecules activation
Junwang Tang, Tsinghua University, China