Coordination substances called dioxygen complexes have O 2 as a ligand. Oxygen-transporting proteins including myoglobin, haemoglobin, hemerythrin, and hemocyanin serve as inspiration for the research of these substances. Many of the complexes formed by transition metals and O 2 are reversible. About 20% by volume of the earth's atmosphere is made up of dioxygen. With two unpaired electrons, one in each of the doubly degenerate *HOMOs, molecular oxygen is a ground-state triplet. Formally, molecular oxygen possesses a double bond and is a potent oxidant in terms of thermodynamics. However, because of spin conservation, the interaction of O2 with ground-state singlet molecules is kinetically unfavourable and necessitates the reaction with additional ground-state radicals, such as flavins, pterins, or metal ions.
Michael Stockenhuber
University of Technology Sydney, Australia
Stanislaw Dzwigaj
Sorbonne University, France
Victor Cerda
University of the Balearic Island, Spain
Dai Yeun Jeong
Asia Climate Change Education Center and Jeju National University, Korea, Republic of
Eva Faillace
University of Corsica, France
Eduardo Bernad
Aragon Hydrogen Foundation, Spain
Anastasia Eleni Eleana Kordouli
University of Patras, Greece
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Vladislav Sadykov, Boreskov Institute of Catalysis and Novosibirsk State University, Russian Federation
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Stanislaw Dzwigaj, Sorbonne University, France
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Victor John Law, Technical University Dublin, Ireland
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Sergey Suchkov, N.D. Zelinskii Institute for Organic Chemistry of the Russian Academy of Sciences, Russian Federation
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Malayil Gopalan Sibi, VSB-Technical University of Ostrava, Czech Republic
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