Because silver is more affordable than other pricey transition metals (TM), has great selectivity and stability, and is ecologically friendly, it plays a significant role in organic synthesis. These metal-catalyzed cycloaddition processes, which are essential tools in synthetic chemistry, include silver-catalyzed events as a subset. Azomethine ylides are shown as the most prevalent resonance form with an iminium ion and a carbon-centered anion adjacent to it. They are nitrogen-based 1,3-dipoles. In general, a high temperature of up to 100 °C is needed for the Huisgen 1,3-dipolar cycloaddition of terminal alkynes with azides, which yields a mixture of 1,4- and 1,5-disubstituted triazole isomers. In a polymeric structure known as silver dicyanamide, metal ions are spirally connected by dicyanamide. With azomethine imine, the silver-catalyzed cycloaddition was also shown.
Stanislaw Dzwigaj
Sorbonne University, France
Dai Yeun Jeong
Asia Climate Change Education Center and Jeju National University, Korea, Republic of
Samy Ponnusamy
MilliporeSigma, United States
Gustaaf Schoukens
Ghent University, Belgium
Valyaev Alexander
Nuclear Safety Institute of the Russian Academy of Sciences, Russian Federation
Vladimir G Chigrinov
Hong Kong University of Science and Technology, Hong Kong
Sujit Kumar Bandyopadhyay
Variable Energy Cyclotron Centre, India
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